Statistical approach to determine the salinized ground water flow path and hydrogeochemical features around the underground LPG cavern,Korea     

Jeongho Lee  Ji‐Hoon Kim  Hun‐Mi Kim  Ho‐Wan Chang 《水文研究》2007,21(26):3615-3626

The ground water flow path of the coastal area in the Yellow Sea, Korea, was interpreted using both the cross‐correlation analysis of hydraulic properties and the principal component analysis (PCA) of ground water chemistry. Data was obtained from observation wells in the underground liquefied petroleum gas (LPG) cavern constructed in the coastal area of Pyeongtaek. Cross‐correlation results showed that the operating pressure became more influenced on artificial factors for the variation of the groundwater level of the study area (45–66% of correlation coefficient) even though its affecting area was limited to the region with fractures or faults, and also showed that the delay time from the variation of operating pressure to the fluctuation of ground water level were relatively long periods (28–31 days). Three hydrogeochemical events (encrusted cement dissolution, host rock dissolution, and seawater intrusion), which were dominantly influenced on ground water quality, could be induced from the result of PCA. Quantitative evaluation for these events using the mixed equation with principal component scores suggest that the dissolution of encrusted cement materials was the predominant factor (39·0% of the total mixed proportion) to change the chemical composition of the seepage water during the ground water flow from the observation wells to the cavern. Integration of the statistical results also imply that ground water flow and hydrogeochemistry were predominantly affected by artificial factors such as cavern operation pressure and dissolution of encrusted cement materials, which were interdependent factors on the observation wells with high cross‐correlation coefficients and pH. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

基于非均匀水体对比度传输方程的海水透明度计算试验          下载免费PDF全文

李妍  陈希  于斌  钟奕飞 《大气科学学报》2014,37(6):767-771

针对均匀水体假设的海水透明度经验计算公式不具有普适性的缺点,将海水在垂直方向上分为若干光学性质相近的均匀层,推导出非均匀水体中目标对比度传输方程,在此基础上,建立了海水透明度的计算模型。利用BROKE_WEST_ACS实测的海水固有光学性质数据和透明度盘观测数据,对计算模型进行了数值试验和效果分析。结果表明:模型计算值与透明度盘实测值平均相对误差为9.1%;该模型既克服了透明度盘测量易受天气状况和人眼差异影响较大的缺点,又突破了均匀水体透明度计算方法的局限性。  相似文献   

一种基于相对梯度法的海水温度分层模型     

赵宁  韩震  王嵩 《中国海洋大学学报(自然科学版)》2014,44(9):25-29,52

提出了一种以海表面温度为输入参数的海水温度分层模型。以2005—2012年的Argo气候态数据集与Argo浮标数据为基础,采用相对梯度法对海水温度垂向结构进行了分层,并据此获取了各层拟合方程所需的参数,包括:混合层深度、混合层梯度、温跃层上界深度、温跃层下界深度、深层大洋起始深度以及方程拟合系数。本文通过世界大洋数据库09版的CTD、XBT实测剖面数据对模型进行了检验。检验结果表明,该模型可以有效地对海水温度结构进行模拟,特别是400m以上的中上层大洋。模拟结果的总体均方根差(RMSE)为0.778℃,而在水深400m以上的中上层区域误差为0.494℃。  相似文献   

Measurement of trace nitrate concentrations in seawater by ion chromatography with valve switching     

杜娟  法芸  郑岳  李学兵  杜芳林  杨海燕 《中国海洋湖沼学报》2014,32(3):732-736

An ion chromatographic method with a valve switching facility was developed to determine trace nitrate concentrations in seawater using two pumps, two different suppressors, and two columns. A carbohydrate membrane desalter was used to reduce the high concentrations of sodium salts in samples. In this method, trace nitrate was eluted from the concentrator column to the analytical columns, while the matrix flowed to waste. Neither chemical pre-treatment nor sample dilution was required. In the optimized separation conditions, the method showed good linearity （R〉0,99） in the 0.05 and 50 mg/L concentration range, and satisfactory repeatability （RSD〈5%, n=6）. The limit of detection for nitrate was 0.02 mg/L. Results showed that the valve switching system was suitable and practical for the determination of trace nitrate in seawater.  相似文献   

Assessing seawater quality with a variable fuzzy recognition model     

柯丽娜  王权明  盖美  周惠成 《中国海洋湖沼学报》2014,32(3):645-655

With the rapid development of the marine economy industry, human exploitation of marine resources is increasing, which is contributing to the growing trend of eutrophication and frequent occurrence of red tide. Accordingly, investigations of seawater quality have attracted a great deal of attention. This study was conducted to construct a seawater environmental quality assessment model based on the variable fuzzy recognition model. The uncertainty and ambiguity of the seawater quality assessment were then considered, combining the monitoring values of evaluation indicators with the standard values of seawater quality. Laizhou Bay was subsequently selected for a case study. In this study, the correct variable model for different parameters was obtained according to the linear and nonlinear features of evaluation objects. Application of the variable fuzzy recognition model for Laizhou Bay, water quality evaluation and comparison with performance obtained using other approaches revealed that the generated model is more reliable than traditional methods, can more reasonably determine the water quality of various samples, and is more suitable for evaluation of a multi-index, multi-level, nonlinear marine environment system; accordingly, the generated model will be an effective tool for seawater quality evaluation.  相似文献   

Marine bacterium strain screening and pyrethroid insecticide-degrading efficiency analysis     

孙爱丽  刘菁华  史西志  李德祥  陈炯  唐道军 《中国海洋湖沼学报》2014,32(5):1029-1035

A pyrethroid insecticide-degrading bacterium, strain HS-24, was isolated from an offshore seawater environment. The strain, which can degrade cypermethrin(CYP) and deltamethrin(DEL), was identified as Methylophaga sp. The optimal culture and degradation conditions for CYP and DEL by strain HS-24 is pH 7 at 28°C. Under optimum culture conditions, strain HS-24 exhibited a broad degradation concentration range of 100, 200, 400, 600, and 800 mg/L for CYP and DEL. The metabolic intermediates were analyzed by NMR, which provided strong evidence that CYP and DEL removal occurred mainly because of a biological process. The toxicity of the degradation products of strain HS-24 was studied simultaneously by measuring the light output of the luminescence bacterium. This demonstrated that the biodegradation ability of strain HS-24 significantly decreased the toxicity of CYP- and DEL-contaminated aquaculture seawater. Finally, the findings of this paper indicate that strain HS-24 is thus revealed as a biological agent for the remediation of marine aquatic environments.  相似文献   

基于指标规范值的海水水质评价的SVR模型   总被引：1，自引：0，他引：1  

梁晓龙  李祚泳  汪嘉杨 《成都信息工程学院学报》2014,(2):208-212

为了建立具有普适通用的海水水质评价的支持向量机模型,在设置各指标参照值和指标规范变换式,并对指标进行规范变换的基础上,应用免疫进化优化算法,建立基于指标规范值的海水水质评价的回归支持向量机模型。将优化好的模型用于珠江口海水水质的评价,其评价结果与BP神经网络的评价结果基本一致,从而表明基于指标规范值的支持向量机模型用于海水水质评价是可行的,且该模型较传统的支持向量机评价模型具有较好的普适性和通用性。  相似文献   

Research on the critical conditions for clay particle release during saline aquifer freshening process     

Xilai Zheng  Ran Chen 《中国海洋大学学报(英文版)》2014,13(4):628-636

Water sensitivity phenomenon occurs during saline aquifer freshening process in seawater intrusion area, and clay particles released in the phenomenon can damage the infiltration capacity of the aquifer. In order to find out the factors and mechanisms for clay particle release, laboratory column infiltration experiments simulating saline aquifer freshening process were designed to measure the critical conditions(critical flow velocity, critical salt concentration and critical ionic strength) and force analysis for clay particle according to DLVO electric double layer theory was employed to illustrate the mechanisms for particle release. The research results showed that critical flow velocity for clay particle release is influenced by salt concentration of injecting solution. When salt concentration of injecting solution is very high, clay particles are not released, indicating that there does not exist a critical flow velocity in this situation. As salt concentration of injecting solution decreases, particles start to be released. The critical salt concentration for clay particle release is 0.052 mol L-1 in our work, which was determined by a constant-flux experiment for stepwise displacement of high concentration Na Cl solution. The critical ionic strength for clay particle release decreases as Ca2+ molar content percentage of the mixed solution of Na Cl and Ca Cl2 increases following the first-order exponential decay equation y = 0.0391e-0.266 x + 0.0015.  相似文献   

Molecularly imprinted polymers for selective extraction of crystal violet from natural seawater coupled with high-performance liquid chromatographic determination     

LIAN Ziru  and WANG Jiangtao 《中国海洋大学学报(英文版)》2014,13(2):236-242

Molecularly imprinted polymers(MIPs) were prepared by the bulk polymerization using crystal violet as the template molecule, and the methacrylic acid and ethylene glycol dimetheacrylate as functional monomer and cross-linker, respectively. Systematic investigations of synthetic conditions were conducted. The surface morphology and recognition mechanism of the obtained polymers were studied using scanning electron microscope and spectrophotometric analysis. MIPs showed high affinity to template molecule and were successfully applied as special solid-phase extraction sorbent for selective extraction of crystal violet from natural seawater. An off-line molecularly imprinted solid-phase extraction(MISPE) method followed by high-performance liquid chromatography with diodearray detection for the analysis of crystal violet was also established. MISPE columns have good recoveries for crystal violet standard solutions and good linearity was obtained over the concentration range of 0-200 μg L-1(R2 0.99). Finally, two natural seawater samples were investigated. The recoveries of spiked seawater on the MISPE columns were from 44.47% to 62.34%, the relative standard deviation(n=3) being in the range of 2.89%-5.96%.  相似文献   

Evaluating the fitness for use of spatial data sets to promote quality in ecological assessment and monitoring     

Isabel Pôças  João Gonçalves  Bruno Marcos  Joaquim Alonso  Pedro Castro  João P. Honrado 《International journal of geographical information science》2014,28(11):2356-2371

This article proposes and illustrates a practical methodological framework to evaluate the fitness for use of spatial data sets for environmental and ecological applications, focusing on user requirements for specified application contexts. The methodology is based on the use of metadata to analyze similarity between the data characteristics and the user’s needs or expectations for several quality indicators. Additionally, the concept of ‘critical factors’ is introduced in this framework, allowing users to define which quality indicators have greater importance given their own requirements or expectations and the specified application contexts. The proposed methodology further allows integrating and interconnecting the spatial data quality (SDQ) evaluation methodology with metadata geoportals in WebGIS platforms, facilitating its operation by users from non-spatial disciplines and with often limited expertise on this subject. Examples of the evaluation of fitness for use for specific application contexts within the project BIO_SOS (‘Biodiversity Multi-SOurce Monitoring System: From Space To Species’ FP7 project) are presented. By providing a prompt and straightforward evaluation tool, the proposed methodology can encourage the implementation of SDQ evaluation routines in ecological assessment and monitoring programs, promoting a more adequate use of geospatial data and ultimately contributing to well-supported policy and management decisions.  相似文献